"The choices we make will be decisive for the Greek people," he said, adding that the euro was vital for prosperity.
Debt-laden Greece must quickly approve a EU bailout to secure vital loans.
Mr Papademos, a former European Central Bank vice-president, was named on November 10 after protracted talks. His cabinet is to be sworn in on November 11.
Mr Papademos, who is not a member of parliament, will head the interim government until elections can take place in February.
He will clearly have strong European support given his past experience – but there will be some Greeks who see Europe’s hand a little too clearly behind his appointment.
Reports say he has accepted that the current Finance Minister, Evangelos Venizelos, remains in place. The exact make-up of the new coalition government is yet to be agreed.
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